发射光谱载体蒸馏法测定地质样品中微量硼铍锡银

选择了适合的缓冲剂,利用载体蒸馏法将被测元素与基体元素分离,使Be转变为易挥发的氟化物与B、Sn、Ag同时蒸发;降低了谱线背景及元素检出限;加入内标元素Au、Bi,提高了方法的准确度和精密度;采用普通 3mm×3mm×0.7mm杯型电极,装样量少,操作简单。方法检出限(wB/10-6)分别可达B1.5、Be0.3、Sn0.8、Ag0.02;准确度(Δlog C)基本在-0.05～0.05,精密度(RSD,n=8)为2.9%～17%。     

油气圈闭与鄂尔多斯盆地北部铀成矿关系探讨

鄂尔多斯盆地北部的伊盟隆起区 ,特别是杭锦旗至东胜一带的地层发育大量的圈闭 ,它们是油气聚集成藏的场所。本文剖析了这些圈闭的类型和成因 ,指出它们是盆地北部天然气运移的有利指向区 ,是还原性气体的储存库和重要的扩散源 ;油气渗出和含氧含铀水渗入的交汇部位是铀成矿的有利场所。因此 ,查明圈闭和断裂构造 ,对分析油气运移方向及砂岩型铀矿预测具有实际意义     

电法软件设计中交互与可视化技术应用

电法软件中的可视化技术包括电法数据交互编辑修改、样点曲线和一维地电模型的可视化和人机交互、断面图等值线与颜色填充、二维地电模型人机交互建模、三维异常体交互建模.这些技术为实现一个实用、快速、操作方便的电法软件系统提供了可靠的保证.     

Transformation of garnet epidote amphibolite to eclogite, western Dabie Mountains, China

Omphacite and garnet coronas around amphibole occur in amphibolites in the Hong'an area, western Dabie Mountains, China. These amphibolites consist of an epidote–amphibolite facies assemblage of amphibole, garnet, albite, clinozoisite, paragonite, ilmenite and quartz, which is incompletely overprinted by an eclogite facies assemblage of garnet, omphacite and rutile. Coronas around amphibole can be divided into three types: an omphacite corona; a garnet–omphacite–rutile corona; and, a garnet–omphacite corona with less rutile. Chemographic analysis for local reaction domains in combination with petrographical observations show that reactions Amp + Ab + Pg = Omp +Czo + Qtz + H₂O, and Amp + Ab = Omp ± Czo + Qtz + H₂O may lead to the development of omphacite coronas. The garnet–omphacite–rutile corona was formed from the reaction Amp + Ab + Czo + Ilm ± Qtz = Omp + Grt + Rt + H₂O. In garnet–omphacite coronas, the garnet corona grew during an early stage of epidote amphibolite facies metamorphism, whereas omphacite probably formed by the reactions forming the omphacite corona during the eclogite facies stage. It is estimated that these reactions occurred at 0.8–1.4 GPa and 480–610 °C using the garnet–clinopyroxene thermometer and omphacite barometer in the presence of albite.     

Conditions of pocket formation in the Oktyabrskaya tourmaline-rich gem pegmatite (the Malkhan field, Central Transbaikalia, Russia)

Coexisting melt (MI), fluid-melt (FMI) and fluid (FI) inclusions in quartz from the Oktaybrskaya pegmatite, central Transbaikalia, have been studied and the thermodynamic modeling of PVTX-properties of aqueous orthoboric-acid fluids has been carried out to define the conditions of pocket formation. At room temperature, FMI in early pocket quartz and in quartz from the coarse-grained quartz–oligoclase host pegmatite contain crystalline aggregates and an orthoboric-acid fluid. The portion of FMI in inclusion assemblages decreases and the volume of fluid in inclusions increases from the early to the late growth zones in the pocket quartz. No FMI have been found in the late growth zones. Significant variations of solid/fluid ratios in the neighboring FMI result from heterogeneous entrapment of coexisting melts and fluids by a host mineral. Raman spectroscopy, SEM EDS and EMPA indicate that the crystalline aggregates in FMI are dominated by mica minerals of the boron-rich muscovite–nanpingite CsAl₂[AlSi₃O₁₀](OH,F)₂ series as well as lepidolite. Topaz, quartz, potassium feldspar and several unidentified minerals occur in much lower amounts. Fluid isolations in FMI and FI have similar total salinity (4–8 wt.% NaCl eq.) and H₃BO₃ contents (12–16 wt.%). The melt inclusions in host-pegmatite quartz homogenize at 570–600 °C. The silicate crystalline aggregates in large inclusions in pocket quartz completely melt at 615 °C. However, even after those inclusions were significantly overheated at 650±10 °C and 2.5 kbar during 24 h they remained non-homogeneous and displayed two types: (i) glass+unmelted crystals and (ii) fluid+glass. The FMI glasses contain 1.94–2.73 wt.% F, 2.51 wt.% B₂O₃, 3.64–5.20 wt.% Cs₂O, 0.54 wt.% Li₂O, 0.57 wt.% Ta₂O₅, 0.10 wt.% Nb₂O₅, 0.12 wt.% BeO. The H₂O content of the glass could exceed 12 wt.%. Such compositions suggest that the residual melts of the latest magmatic stage were strongly enriched in H₂O, B, F, Cs and contained elevated concentrations of Li, Be, Ta, and Nb. FMI microthermometry showed that those melts could have crystallized at 615–550 °C.

Crystallization of quartz–feldspar pegmatite matrix leads to the formation of H₂O-, B- and F-enriched residual melts and associated fluids (prototypes of pockets). Fluids of different compositions and residual melts of different liquidus–solidus P–T-conditions would form pockets with various internal fluid pressures. During crystallization, those melts release more aqueous fluids resulting in a further increase of the fluid pressure in pockets. A significant overpressure and a possible pressure gradient between the neighboring pockets would induce fracturing of pockets and “fluid explosions”. The fracturing commonly results in the crushing of pocket walls, formation of new fractures connecting adjacent pockets, heterogenization and mixing of pocket fluids. Such newly formed fluids would interact with a primary pegmatite matrix along the fractures and cause autometasomatic alteration, recrystallization, leaching and formation of “primary–secondary” pockets.     

预应力锚索技术在大型水库除险加固工程中的应用

介绍了无粘结预应力锚固技术在吉林省二龙山水库除险加固工程中的应用。对造孔、编索、下索、张拉等工艺进行了详细介绍。     

基于宽带网的河南省太阳紫外线强度监测系统研究

使用自主研发的Gstar-Ⅱ型太阳紫外线监测仪,建立基于宽带网的河南省城市紫外线强度监测系统。太阳紫外线强度自动监测站将从紫外线传感器获得的气象要素信息传给本地专用计算机,进行数据处理和编码,然后通过互联网把数据信息送到数据业务中心站,数据业务中心站具有对接收数据进行初步处理和进库的功能;各级气象台站可以很方便地通过宽带Internet网WinSock协议进入数据处理中心,按照自己的要求调用全省紫外线强度历史和实时资料,为本地紫外线预报提供有力的科学依据和手段。     

A study on the focal parameters of Shidian M =5.9 earthquake sequences in 2001

On the basis of about 300 earthquake wave forms observed in the Shidian M _S=5.9 sequences on April 12, 2001 recorded in Kunming Digital Seismic Network, the spectra of shear wave have been used to estimate the focal parameters of these earthquake sequences. The results show that within the magnitude range of 1.5–5.3, the seismic moments are 10¹⁰–10¹⁶ N·m, the corner frequencies are 0.2–0.8 Hz, radii of the focal rupture are 200–2 500 m and the stress drops are 0.1×10⁵–20×10⁵Pa. Through the statistical analyses of variation of corner frequency f _c and stress drop Δσ with time, it is discovered that the average corner frequency of the foreshock sequences is obviously lower than that of the aftershock sequences. Contrarily, the average stress drops Δσ of the foreshock sequences are clearly higher than that of the aftershocks. It is considered that these variation characteristics of average corner frequency and stress drops before and after the main shock have index significance to the precursory information before a strong earthquake. The higher stress drops for the foreshock sequences show that the higher shear stresses have been stored in the area of main shock. After the main shock, most of the stresses have been released, so the aftershock sequences show a rupture process of lower stresses. Foundation item: Scientific and Technological Key Project of Yunnan Province (2001NG46)     

Migrating pingos in the permafrost region of the Tibetan Plateau, China and their hazard along the Golmud–Lhasa railway

Most pingos in the permafrost region of the high northern Tibetan Plateau form along active fault zones and many change position annually along the zones and thus appear to migrate. The fault zones conduct geothermal heat, which thins permafrost, and control cool to hot springs in the region. They maintain ground-water circulation through broken rock in an open system to supply water for pingo growth during the winter in overlying fluvial and lacustrian deposits. Springs remain after the pingos thaw in the summer. Fault movement, earthquakes and man's activities cause the water pathways supplying pingos to shift and consequently the pingos migrate.

The hazard posed to the new Golmud–Lhasa railway across the plateau by migrating pingos is restricted to active fault zones, but is serious, as these zones are common and generate large earthquakes. Pingos have damaged the highway and the oil pipeline adjacent to the railway since 2001. One caused tilting and breaking of a bridge pier and destroyed a highway bridge across the Chumaerhe fault. Another has already caused minor damage to a new railway bridge. Furthermore, the construction of a bridge pier in the North Wuli fault zone in July–August 2003 created a conduit for a new spring, which created a pingo during the following winter. Measures taken to drain the ground-water via a tunnel worked well and prevented damage before the railway tracks were laid. However, pier vibrations from subsequent train motion disrupted the drain and led to new springs, which may induce further pingo growth beneath the bridge.

The migrating pingos result from active fault movement promoting artesian ground-water circulation and changing water pathways under the seasonal temperature variations in the permafrost region. They pose a serious hazard to railway construction, which, in turn can further disturb the ground-water conduits and affect pingo migration.     

Pristine and reacted surfaces of pyrrhotite and arsenopyrite as studied by X-ray absorption near-edge structure spectroscopy

Fe L-, S L-, and O K-edge X-ray absorption spectra of natural monoclinic and hexagonal pyrrhotites, Fe_1-xS, and arsenopyrite, FeAsS, have been measured and compared with the spectra of minerals oxidized in air and treated in aqueous acidic solutions, as well as with the previous XPS studies. The Fe L-edge X-ray absorption near-edge structure (XANES) of vacuum-cleaved pyrrhotites showed the presence of, aside from high-spin Fe²⁺, small quantity of Fe³⁺, which was higher for a monoclinic mineral. The spectra of the essentially metal-depleted surfaces produced by the non-oxidative and oxidative acidic leaching of pyrrhotites exhibit substantially enhanced contributions of Fe³⁺ and a form of high-spin Fe²⁺ with the energy of the 3d orbitals increased by 0.3–0.8 eV; low-spin Fe²⁺ was not confidently distinguished, owing probably to its rapid oxidation. The changes in the S L-edge spectra reflect the emergence of Fe³⁺ and reduced density of S s–Fe 4s antibonding states. The Fe L-edge XANES of arsenopyrite shows almost unsplit e_g band of singlet Fe²⁺ along with minor contributions attributable to high-spin Fe²⁺ and Fe³⁺. Iron retains the low-spin state in the sulphur-excessive layer formed by the oxidative leaching in 0.4 M ferric chloride and ferric sulphate acidic solutions. The S L-edge XANES of arsenopyrite leached in the ferric chloride, but not ferric sulphate, solution has considerably decreased pre-edge maxima, indicating the lesser admixture of S s states to Fe 3d orbitals in the reacted surface layer. The ferric nitrate treatment produces Fe³⁺ species and sulphur in oxidation state between +2 and +4.